Asphyxiation from Refrigerant Accumulation in Confined Spaces
HighRefrigerants are heavier than air and displace oxygen when released in confined or poorly ventilated spaces. Plant rooms, cool rooms, under-floor spaces, ceiling cavities, and service pits can accumulate refrigerant from leaks or during recovery operations. Oxygen levels below 19.5% cause rapid unconsciousness and death. Technicians entering spaces where refrigerant has leaked face immediate asphyxiation risk as refrigerant displaces breathing air at ground level where faces are positioned when kneeling or bending. Large refrigerant leaks in confined spaces can reduce oxygen to fatal levels within minutes.
Consequence: Rapid unconsciousness and death from oxygen deficiency, brain damage from hypoxia if rescue is delayed, multiple casualties if rescue personnel enter contaminated space without breathing apparatus, and long-term neurological damage in survivors of asphyxiation incidents.
Cold Burns from Liquid Refrigerant Contact
HighLiquid refrigerant released from pressurised systems undergoes rapid expansion and evaporative cooling to temperatures as low as -50°C depending on refrigerant type. Skin contact with liquid refrigerant or refrigerant spray from leaks causes immediate freeze burns similar to frostbite. Eyes exposed to refrigerant spray can suffer permanent vision damage. Gloves and clothing contaminated with liquid refrigerant cause prolonged cold exposure. Rapid depressurisation when disconnecting refrigerant lines releases refrigerant spray toward worker faces and hands.
Consequence: Severe cold burns requiring skin grafts and prolonged treatment, permanent vision loss or impairment from eye exposure, tissue necrosis requiring amputation in extreme cases, scarring and disfigurement from deep freeze injuries, and chronic pain from nerve damage in affected tissues.
High-Pressure System Failures and Component Rupture
HighRefrigerant systems operate at high pressures often exceeding 2000kPa on high-pressure sides and 1500kPa on low-pressure sides. Overpressurisation from overcharging, blockages, or exposure to heat causes pressure vessel failure. Hoses, fittings, and equipment subjected to pressures exceeding ratings can rupture explosively releasing refrigerant and metal fragments. Refrigerant cylinders exposed to heat or flame can catastrophically fail with explosion force. Incorrect connection of gauges or recovery equipment to high-pressure systems exceeding equipment ratings causes equipment failure.
Consequence: Explosive rupture causing metal fragmentation and penetrating injuries, refrigerant release causing asphyxiation in enclosed spaces, severe cold burns from released refrigerant, impact injuries from failed components, and fire if flammable refrigerants are released near ignition sources creating explosion risk.
Toxic Decomposition Products from Refrigerant Heating
MediumRefrigerants exposed to flames, hot surfaces above 250°C, or electrical arcs decompose forming highly toxic products including hydrofluoric acid, hydrochloric acid, phosgene gas, and other halogenated compounds. Brazing or welding refrigerant lines containing residual refrigerant generates toxic fumes. Refrigerant leaks near open flames, gas appliances, or electrical equipment create toxic decomposition products. These compounds cause severe respiratory irritation, chemical pneumonitis, and long-term lung damage even from brief exposures.
Consequence: Chemical pneumonitis requiring hospitalisation and prolonged treatment, permanent lung damage and reduced respiratory capacity, acute respiratory distress requiring ventilation support, chronic respiratory sensitisation, and long-term health effects including pulmonary fibrosis from severe exposures.
Flammable Refrigerant Fire and Explosion Risks
HighHydrocarbon refrigerants including R290 (propane), R600a (isobutane), and R1270 (propylene) are highly flammable with ignition energies as low as 0.25mJ. Leaks in confined spaces create flammable atmospheres that can ignite from electrical equipment, static discharge, hot surfaces, or open flames. Flammable refrigerant concentrations between lower explosive limit (LEL) and upper explosive limit (UEL) present explosion risks. Some newer low-GWP refrigerants are classified as A2L (mildly flammable) requiring additional safety measures. Cylinder storage near heat sources or ignition sources presents fire risks.
Consequence: Fire and explosion causing severe burns and inhalation injuries, building fires extending beyond immediate work area, fatalities to workers and building occupants, extensive property damage from explosions, and secondary injuries from structural collapse or fleeing occupants during evacuations.
Cardiac Sensitisation from High Refrigerant Concentrations
MediumCertain refrigerants including HCFCs and HFCs sensitise heart muscle to adrenaline when inhaled at high concentrations (typically above 10% by volume). This sensitisation increases risk of sudden cardiac arrest particularly if worker experiences stress, exerts physically, or receives adrenaline shock during refrigerant exposure. Cardiac sensitisation can occur at concentrations below those causing asphyxiation. Workers with pre-existing cardiac conditions face increased risk.
Consequence: Sudden cardiac arrest during or shortly after refrigerant exposure, death if defibrillation and CPR are not immediately available, long-term cardiac rhythm abnormalities in survivors, and increased risk for workers performing physically demanding tasks while exposed to refrigerant concentrations.
Pressure Equipment Connection Failures and Blowback
MediumConnecting and disconnecting refrigerant hoses, gauge manifolds, and recovery equipment to pressurised systems presents risks of connection failure, hose blowoff, and refrigerant spray release. Improperly tightened fittings blow off under pressure. Damaged or degraded hoses fail explosively. Quick-connect fittings may release under vibration if not properly locked. Attempting to disconnect pressurised hoses releases refrigerant spray toward worker. Cross-threading or incorrect adapter use causes fitting failure under pressure.
Consequence: Cold burns from refrigerant spray released during connection failures, eye injuries from refrigerant or oil spray hitting face, hand and finger injuries from recoil of failed hoses under pressure, refrigerant release causing environmental violations and equipment damage, and equipment damage from uncontrolled refrigerant loss.